TUBALL™ nanotubes provide stable anti-static performance to silicone compounds while retaining mechanical properties and minimally impacting the host matrix.
TUBALL™ graphene nanotubes are applied via the easy-to-use additive TUBALL™ MATRIX, which is a line of concentrates based on polymer carriers and pre-dispersed TUBALL™ graphene nanotubes.
In contrast to other conductive agents, TUBALL™ graphene nanotubes are a versatile conductive agent offering good performance on all key parameters.
Parameter |
Carbon black |
Metallic |
MWCNT |
|
Working dosage |
10 wt.% |
10 wt.% |
3 wt.% |
2 wt.% |
Resistance requirements (volume Resistivity) |
105–107 Ω•сm |
|||
Resistance result (volume Resistivity) |
106–109 Ω•сm |
105–107 Ω•сm |
105–107 Ω•сm |
105–107 Ω•сm |
Black dots on surface |
only black available |
none |
only black available |
none |
Available color range |
none |
limited |
none |
wide |
Resistance remains stable after abrasion on surface |
no |
yes |
yes |
yes |
Influence on mechanical performance |
strong negative |
strong negative |
strong negative |
none |
Influence to rheology |
strong negative* |
negative* |
strong negative* |
none |
Dust formation during production |
yes |
yes |
yes/none |
none |
‘Hot spots’ |
yes |
possible |
possible |
none |
Stable resistance over time |
no |
yes |
yes |
yes |
Longer life cycle of compound and molded parts |
no |
no |
no |
yes |
Carbon release on surface |
yes |
none |
none |
none |
Cost of anti-static property |
comparable |
high |
comparable |
comparable |
* Formulation design required (adjustment of curing system).
The wide range of color options makes it possible to provide various parts to the market where anti-static properties are required.
Colored anti-static silicone rubber
Volume resistivity of 103–105 Ω•cm. TUBALL™ loading 0.2–0.05%
TUBALL™ nanotubes, in contrast to traditional conductive agents, minimize the impact on compound elasticity and on tensile parameters, viscosity and rheological properties.
Mechanical properties of anti-static LSR with 4 wt.% of TUBALL™ MATRIX 601
When using carbon black, because of the high concentration required (10% or more) and the spherical shape of the particles, a phenomenon known in the industry as “carbon release” takes place, where the conductive additive is present on the surface of the sample.
In contrast, graphene nanotubes, owing to their greater length-to-diameter ratio, are not released to the surface.
If materials will be used under conditions of deformation, it is important that stable resistivity is maintained. With TUBALL™ MATRIX, the resistivity is maintained below the target value even after stress-strain.
High dynamic pressure applications – Anti-static LSR with 1 wt.% of TUBALL™ MATRIX 601
TUBALL™ MATRIX can be diluted into compounds through the use of standard silicone compounding equipment (2-roll mill, kneader). Other approaches for masterbatch dilution may be used provided that their mixing efficiency is sufficient.
More information about the key parameters for masterbatch dilution and compound processing can be found in the processing guidelines.
Conductive colored HCR: Processing guidelines for TUBALL™ MATRIX 605
Conductive LSR with TUBALL™ MATRIX - Processing guide
Conductive Silicones - LSR, RTV, HCR and PSA
Electrical resistivity guideline: measurement, standards & troubleshooting
Contact us to discuss your project specifications or to request a TUBALL MATRIX sample