TUBALL™ nanotubes provide superior electrical conductivity to silicone compounds while retaining mechanical properties and minimally impacting the host matrix.
TUBALL™ graphene nanotubes are applied via the easy-to-use additive TUBALL™ MATRIX, which is a line of concentrates based on polymer carriers and pre-dispersed TUBALL™ graphene nanotubes.
In contrast to other conductive agents, TUBALL™ graphene nanotubes are a versatile conductive agent offering good performance on all key parameters.
Parameter |
Highly conductive carbon black |
Metallic |
MWCNTs |
|
Working dosage |
8 wt.% |
30 wt.% |
5–10 wt.% |
4 wt.% |
Resistance requirements (volume Resistivity) |
<50 Ω·сm |
|||
Resistance achieved |
10–102 Ω·сm |
<30 Ω·сm |
<100 Ω·сm |
<50 Ω·сm |
Influence on mechanical performance |
strong negative |
strong negative |
strong negative |
none |
Influence on viscosity and extrusion rate |
strong negative |
negative |
strong negative |
acceptable |
Influence on rheology |
strong negative |
negative |
strong negative |
none |
Dust formation during production |
yes |
yes |
yes (but none in the case of a masterbatch) |
none |
Complicated processing (separate production unit, additional compounding stages) |
yes |
no |
yes |
no |
“Hot spots” (resistance varies) |
yes |
none |
possible |
none |
Stable resistance over time |
no |
yes |
yes |
yes |
Longer life cycle of compound and molded parts |
no |
no |
no |
yes |
Carbon release on surface |
yes |
none |
none |
none |
Cost of anti-static property |
comparable |
high |
comparable |
comparable |
When using carbon black, because of the high concentration required (10% or more) and the spherical shape of the particles, a phenomenon known in the industry as “carbon release” takes place, where the conductive additive is present on the surface of the sample.
In contrast, graphene nanotubes, owing to their greater length-to-diameter ratio, are not released to the surface.
If materials will be used under conditions of deformation, it is important that stable resistivity is maintained. With TUBALL™ MATRIX, the resistivity is maintained below the target value even after stress-strain.
High dynamic pressure applications - conductive LSR with 2.5 wt.% of TUBALL™ MATRIX 601
Conductive HCR: TUBALL™ vs carbon black
TUBALL™ nanotubes, in contrast to traditional conductive agents, minimize the impact on compound elasticity and tensile parameters, viscosity and rheological properties.
Physical properties of conductive LSR with 4 wt.% of TUBALL™ MATRIX 601
TUBALL™ MATRIX can be diluted into compounds through the use of standard silicone compounding equipment (2-roll mill, kneader). Other approaches for masterbatch dilution may be used provided that their mixing efficiency is sufficient.
More information about the key parameters for masterbatch dilution and compound processing can be found in the processing guidelines.
Contact us to discuss your project specifications or to request a TUBALL™ MATRIX sample
Conductive colored HCR: Processing guidelines for TUBALL™ MATRIX 605
Conductive LSR with TUBALL™ MATRIX - Processing guide
Conductive Silicones - LSR, RTV, HCR and PSA
Electrical resistivity guidelines
Contact us to discuss your project specifications or to request a TUBALL™ MATRIX sample